咔唑
二苯胺
材料科学
热稳定性
兴奋剂
组合化学
化学
光电子学
光化学
有机化学
冶金
作者
Jian Liu,Heng Zhang,Bingxue Wu,Lixue Sun,Yu Chen,Xueping Zong,Zhe Sun,Song Xue,Mao Liang
出处
期刊:Solar RRL
[Wiley]
日期:2021-10-14
卷期号:5 (12)
被引量:7
标识
DOI:10.1002/solr.202100694
摘要
The extraordinary electronic and structural properties of carbazole make it an important donor for the molecular design of hole transport materials (HTMs). However, the development of peripheral carbazole donors has lagged behind. Herein, a series of low‐cost arylamine‐substituted carbazole donors are synthesized by a one‐step facile method. The effect of the terminal arylamine on the optoelectronic, thermal stability, hole mobility, and photovoltaic properties of the studied carbazole HTMs is also investigated. The diphenylamine‐ and carbazole‐substituted carbazoles possess the orthogonal–planar conformation, endowing the HTMs (M142 and M143) with excellent electronic properties and morphological properties. Consequently, power conversion efficiencies (PCEs) of 19.60% and 20.05% accompanied with a high photovoltage are achieved for M142‐ and M143‐based doped devices, respectively, outperforming the controlled cells based on nonsubstituted carbazole HTM (M145, PCE = 17.25%). Moreover, the devices based on M143 exhibit good long‐term storage, thermal, and light stability. This work provides a simple strategy for molecular design in developing efficient carbazole donors.
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