轮烷
超分子化学
三元运算
超分子聚合物
化学
单体
聚合物
结晶学
高分子化学
立体化学
材料科学
晶体结构
有机化学
计算机科学
程序设计语言
作者
Pan-Qing Zhang,Qian Li,Ze-Kun Wang,Qingxuan Tang,Peipei Li,Wenhao Li,Ge Yang,Yang Bo,Da Ma,Zhan‐Ting Li
标识
DOI:10.1016/j.cclet.2022.06.055
摘要
Here we use nor-seco-cucurbit[10]uril (ns-CB[10]) based ternary complexation to construct [5]rotaxane, linear supramolecular dynamic rotaxane polymers and cubic 3D supramolecular organic framework. A [5]rotaxane is constructed by ns-CB[10], TMeCB[6] and short linear derivatives of 4,4′-bipyridinium (M2). ns-CB[10], CB[7] and long linear derivatives of 4,4′-bipyridinium (M3) self-assemble into a linear supramolecular dynamic rotaxane polymer. ns-CB[10] and tetracationic tetrahedral monomer self-assemble and form a three-dimensional supramolecular organic framework. The above results demonstrate that ns-CB[10]-based ternary complexation is a versatile platform to build various supramolecular systems.
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