阳极
材料科学
锂(药物)
电化学
电极
导电体
相间
化学工程
离子
扩散
电池(电)
阴极
电解质
纳米技术
复合材料
化学
热力学
有机化学
物理化学
生物
工程类
遗传学
医学
功率(物理)
物理
内分泌学
作者
Zhaoyu Zhang,Yufei Zhang,Minghui Ye,Yongchao Tang,Xiaoqing Liu,Cheng Li
标识
DOI:10.1016/j.jpowsour.2022.231795
摘要
SiOx/C composites are highly potential anode alternatives for next-generation lithium-ion batteries (LIBs) owing to their low cost and high theoretical capacity. However, the sluggish lithium-ion diffusion kinetics severely limit their practical capacity and rate performance. Herein, a high-capacity and high-rate anode based on commercial SiOx/C is facilely achieved by in situ constructing a Li+ conductive interphase (LCI) to simultaneously boost the transport efficacy of Li+ ions and buffer the volume expansion. The as-designed, LCI-protected SiOx/C anode delivers an exceptionally high capacity of 1420.9 mAh g−1 at 0.2 A g−1, excellent rate performance (91.4% capacity retention from 0.2 A g−1 to 1 A g−1) and long cycling stability, substantially outstripping the pristine SiOx/C counterpart and most recently reported Si-based electrodes. More importantly, taking advantages of the fast and stable lithiation/delithiation processes, this electrode can also be adapted to further applications at large current densities (766.44 mAh g−1 at 5 A g−1) or high mass loadings (5.02 mAh cm−2 at 0.1 A g−1, ∼3.5 mg cm−2). A full battery with satisfactory electrochemical performance is also demonstrated. The strategy of building ion conductive interphase to subtly tailor the transport behavior of Li+ ions is anticipated to unlock the practical deployment of Si-based LIBs.
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