Silver-catalyzed radical ring-opening of cycloalkanols for the synthesis of distal acylphosphine oxides
化学
催化作用
戒指(化学)
组合化学
有机化学
作者
Cheng-Kun Li,Adedamola Shoberu,Jian-Ping Zou
出处
期刊:Organic chemistry frontiers [The Royal Society of Chemistry] 日期:2022-01-01卷期号:9 (16): 4334-4340
标识
DOI:10.1039/d2qo00359g
摘要
This article reports a novel silver-catalyzed ring-opening approach for the regioselective synthesis of distal acylphosphine oxides; the mechanistic studies reveal the cross-coupling of alkyl and phosphorous-centered radicals.