电致变色
材料科学
伪装
纳米技术
钒
普鲁士蓝
氧化钒
光电子学
电化学
电极
计算机科学
化学
物理化学
人工智能
冶金
作者
Baoshun Wang,Ya Huang,Ying Han,Wenshuo Zhang,Chenhui Zhou,Qinyuan Jiang,Fengxiang Chen,Xueke Wu,Run Liu,Pei Lyu,Shumin Zhao,Fei Wang,Fei Wei
出处
期刊:Nano Letters
[American Chemical Society]
日期:2022-04-26
卷期号:22 (9): 3713-3720
被引量:34
标识
DOI:10.1021/acs.nanolett.2c00600
摘要
Transition metal oxides (TMOs) are promising inorganic electrochromic materials (ECMs) that can be widely used in electronic displays and adaptive camouflage. However, there are still huge challenges for TMOs to simultaneously achieve multicolor transformation capability and good cycling stability. Herein, we assemble Au-modified (0.01 wt %) VxO2x+1 (x > 2) nanoflowers (Au@VxO2x+1 NFs) composed of two-dimensional porous nanosheets containing two valences states of vanadium (V4+ and V5+). The Au@VxO2x+1 NFs exhibits outstanding electrochromic performance with five reversible color transformations (orange, yellow, green, gray, and blue) at a voltage less than 1.5 V and excellent cycling stability (2000 cycles without significant decay). To the best of our knowledge, this is the first time that a single vanadium oxide ECM, rather than a device, realizes five color changes. This work provides a feasible way for the efficient preparation of multicolor electrochromic TMOs. The newly developed Au@VxO2x+1 NFs demonstrate the potential application in adaptive camouflage.
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