Highly effective removal of multi-heavy metals from simulated industrial effluent through an adsorption process employing carboxymethyl-chitosan composites

Monochloroacetic acid precursor-based carboxymethyl chitosan resins were prepared using the chitosan with variant molecular weight. The carboxymethylation assured enhanced active sites on the resin surface, acidic media stability, and henceforth its appropriate constitution to facilitate enhanced multi-heavy metal adsorption-desorption and subsequent regeneration potential. Zn, Pb, and Fe multimetal adsorption properties were investigated. Thereby, kinetic and equilibrium models were sought for their fitness to represent heavy metal sorption data with the preferred complex adsorbate system. The adsorbate system complexity and its constituent co-existing cations significantly influence the sorption characteristics of the mentioned multi-heavy metal ions. The optimal adsorption capabilities for Zn, Pb, and Fe were 238.10 mg g−1, 4.78 mg g−1, and 147.06 mg g−1, respectively. Low-cost acid-base solutions were also considered for the effective regeneration of the resin even after three adsorption-desorption cycles. Prominent findings of the work assured excellent functionality of the carboxymethyl-chitosan resin for the simultaneous lead, iron, and zinc ion elimination from mimicking real-world effluent systems.