光催化
罗丹明B
材料科学
可见光谱
锐钛矿
煅烧
二氧化钛
化学工程
掺杂剂
催化作用
纳米技术
兴奋剂
光化学
无机化学
化学
有机化学
复合材料
工程类
光电子学
作者
Zhengyang Chen,Shui Yu,Jianping Liu,Yamei Zhang,Yuchen Wang,Jiangyi Yu,Ming Yuan,Pengchao Zhang,Wen Li,Jiaoxia Zhang
标识
DOI:10.1016/j.envres.2023.116311
摘要
The organic pollutants in industrial wastewater continuously endanger human health. Therefore, effective treatment of organic pollutants is very urgent. Photocatalytic degradation technology is an excellent solution to remove it. TiO2 photocatalysts are easy to prepare and have high catalytic activity, unfortunately, TiO2 only absorbs ultraviolet light limiting its utilization of visible light. In this study, a facile environmentally friendly synthesis of Ag-coated on micro-wrinkled TiO2-based catalysts in order to extend the absorption of Visible light. Firstly, a fluorinated titanium dioxide precursor was prepared by a one-step solvothermal method, and the precursor was calcined at high temperature in a nitrogen atmosphere to form a carbon dopant, and then a surface silver-deposited carbon/fluorine co-doped TiO2 photocatalyst C/F–Ag–TiO2 was prepared by a hydrothermal method The results showed that the Ag was coated on the wrinkled TiO2 layer and C/F–Ag–TiO2 photocatalyst was synthetized successfully. Benefit from the synergistic effect of doped carbon and fluorine atoms in combination with the quantum size effect of the surface silver nanoparticles, the band gap energy of C/F–Ag–TiO2 (2.56 eV) is obviously lower than anatase (3.2eV). The photocatalyst achieved an impressive degradation rate of 84.2% for Rhodamine B in 4 h, with a degradation rate constant of 0.367 h−1, which was 17 times higher than that of P25 under visible light. Therefore, the C/F–Ag–TiO2 composite is a promising candidate as a highly efficient photocatalyst for environmental remediation.
科研通智能强力驱动
Strongly Powered by AbleSci AI