催化作用
贵金属
离子交换
氧气
无机化学
质子交换膜燃料电池
膜
氧还原反应
碳纤维
材料科学
金属
碱性燃料电池
氮气
离子
化学
化学工程
电化学
物理化学
电极
有机化学
复合数
冶金
复合材料
生物化学
工程类
作者
Qixuan Wang,Ling Wang,Kaixin Wang,Yaohui Chen,Guoqiang Deng,Chenxi Xu
标识
DOI:10.1021/acsaem.4c01580
摘要
Highly reactive, long-term stable, and low-cost non-noble metal–nitrogen–carbon (M–N–C) catalysts have been widely considered as promising catalysts for the oxygen reduction reaction (ORR) in alkaline anion exchange membrane fuel cells (AEMFCs). However, the slow chemical reaction kinetics and poor stability of these catalysts remain the main challenges for their widespread application. Herein, Mo2TiC2–NH4 supports are utilized by loading non-noble metal CoCu–N–C as the ORR catalyst for AEMFCs. The half-wave potential of CoCu–N–C/Mo2TiC2–NH4 reaches 0.87 V and decreases by only 2 mV after 10 000 cycles. The fuel cell peak power density based on the CoCu–N–C/Mo2TiC2–NH4 catalyst is over 500 mW cm–2.
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