电解质
熔盐
电池(电)
盐(化学)
化学工程
材料科学
无机化学
化学
冶金
电极
热力学
有机化学
物理化学
物理
工程类
功率(物理)
作者
Xinyi Sun,Di Wang,Min Han,Wei Li,Haoshen Zhou,Ping He
摘要
Herein, a binary inorganic molten salt electrolyte based on lithium bis(fluorosulfonyl)imide (LiFSI) and potassium bis(fluorosulfonyl)imide (KFSI) is applied to Li-CO2 batteries that can operate under 80 °C. Benefiting from the intrinsic nonvolatility, electrochemical stability, raised ionic conductivity, sufficient solubility and safety, the molten electrolyte endows the Li-CO2 battery with a large discharge capacity of 4612 mA h g-1 and superior rate capability. The introduction of the Ru@Super P carbon cathode further optimizes the discharge capacity (9503 mA h g-1), overpotential (1.15 V), and rate capability.
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