Novel Gas Sensing Approach: ReS2/Ti3C2Tx Heterostructures for NH3 Detection in Humid Environments

Continuous monitoring of ammonia (NH3) in humid environments poses a notable challenge for gas sensing applications because of its effect on sensor sensitivity. The present work investigates the detection of NH3 in a natural humid environment utilizing ReS2/Ti3C2Tx heterostructures as a sensing platform. ReS2 nanosheets were vertically grown on the surface of Ti3C2Tx sheets through a hydrothermal synthetic approach, resulting in the formation of ReS2/Ti3C2Tx heterostructures. The structural, morphological, and optical properties of ReS2/Ti3C2Tx were investigated using various state-of-the-art techniques, including scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, zeta potential, Brunauer–Emmett–Teller technique, and Raman spectroscopy. The heterostructures exhibited 1.3- and 8-fold increases in specific surface area compared with ReS2 and Ti3C2Tx, respectively, potentially enhancing the active gas adsorption sites. The electrical investigations of the ReS2/Ti3C2Tx-based sensor demonstrated enhanced selectivity and superior sensing response ranging from 7.8 to 12.4% toward 10 ppm of NH3 within a relative humidity range of 15–85% at room temperature. These findings highlight the synergistic effect of ReS2 and Ti3C2Tx, offering valuable insights for NH3 sensing in environments with high humidity, and are explained in the gas sensing mechanism.