电催化剂
材料科学
星团(航天器)
纳米
纳米技术
催化作用
Atom(片上系统)
化学物理
化学
计算机科学
物理化学
电化学
电极
生物化学
复合材料
嵌入式系统
程序设计语言
作者
Bingxing Zhang,Yaping Chen,Jianmei Wang,Hongge Pan,Wenping Sun
标识
DOI:10.1002/adfm.202202227
摘要
Abstract Single‐atom catalysts (SACs) have attracted great attention in the field of electrocatalysis due to their exceptional activity, selectivity, 100% atom utilization, and tailorability of active sites at atomic level. The metal–support interactions and interatomic synergies, however, are severely limited due to the isolation of active sites in SACs which hinder their applications in some complex reactions. To this end, supported sub‐nanometer cluster catalysts (SNCCs, <2 nm) with nearly fully exposed active atoms may outperform the SACs in some specific catalytic reactions. The presence of abundant chemical bonds in the clusters can flexibly regulate the support–cluster interaction and build ensemble effect in the sub‐nanometer clusters for different electrocatalysis applications. In this review, recent advances of supported SNCCs in electrocatalysis applications are summarized and discussed for the first time. In particular, the importance of the support–cluster interactions and ensemble effect of the clusters in determining the catalytic performance of SNCCs are highlighted. Lastly, challenges and opportunities in SNCCs electrocatalysis are prospected.
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