Influence of chromium, titanium and tantalum carbides on corrosion resistance of cemented carbides

Homogeneous solid-solution (Ti, Ta, Nb,W)(C,N) powders were synthesized through carbothermal reduction-nitridation method. The effects of (Ti, Ta, Nb,W)(C,N) powders on the microstructure, mechanical properties and corrosion resistance of WC-10Co cemented carbides were investigated using XRD, SEM, electrochemical test and mechanical properties tests. The results showed that cemented carbides with pre-alloyed powder addition had a similar microstructure appearance: weak core/rim structure consisting of solid-solution phase embedded in the WC-Co system. The black core and gray rim, both of which contained similar elements, were identified as (Ti, Ta, Nb,W)(C,N), but the latter contained higher amount of heavy elements.With the addition of (Ti, Ta, Nb,W)(C,N) powders, the density, transverse rupture strength and fracture toughness of samples decreased monotonously. However, the hardness rose sharply at first, reached a peak at 15 wt% solid-solution addition, then slightly decreased, and finally increased again. Results also revealed that increasing (Ti, Ta, Nb,W)(C,N) made the open circuit potential (OCP) in 1 M sulphuric acid solution more negative than that of WC-Co, and all specimens exhibited pseudo-passivation phenomenon in the test solution. In addition, increasing pre-alloyed powders led to decreasing corrosion current density, which implies that (Ti, Ta, Nb,W)(C,N) could remarkably improve the corrosion resistance of WC-Co cemented carbides.