SPECTRAL PROPERTIES OF ZINC AND COBALT MESO-TETRAPHENYLPORPHYRINS IN POLYMER FILMS

The results of studying the spectral properties of zinc and cobalt meso-tetraphenyl-porphyrins included as the modifiers in polymethylmethacrylate, polystyrene and polyvinylchloride films are presented in this article for the first time. It was established that an inert polymer matrix of polyvinylchloride, block polystyrene and polymethylmethacrylate does not affect the spectral properties of tetrapyrrole macroheterocycles, which are included in it. In this case, insignificant bathochromic shift of the absorption bands of the metal complexes in the modified films is recorded, which is probably due to the presence of intermolecular interaction of the metalloporphyrin with the polymer matrix. The method of polymer producing is important for modification of polystyrene or polymethyl methacrylate films. The ignificant changes are observed in the electronic spectra of metalloporphyrins due to the interaction between the modifier and the residual amount of the radical polymerization initiator (benzoyl peroxide) used in the preparation of polymers. Earlier studies showed that the interaction of benzoyl peroxide with zinc and cobalt meso-tetraphenylporphyrinates in solution leads to the formation of the corresponding metalloisoporphyrinates. In this work, the possibility of such structures formation in a polymer matrix is shown for the first time. In this case, in the electronic absorption spectra of the modified films, as in solutions, bands appear in the near IR region. The fluorescent properties of modified films have been studied. It was shown that in the absence of interaction between the components in the film, metalloporphyrins introduced into the polymer matrix retain their ability to fluorescence.