中胚层
超分子化学
化学
分子间力
联吡啶
钯
立体化学
配位复合体
结晶学
金属
分子
晶体结构
液晶
有机化学
聚合物
催化作用
作者
Daniela Pucci,Giovanna Barberio,Alessandra Crispini,Mauro Ghedini,O. Francescangeli
标识
DOI:10.1080/15421400390193864
摘要
Abstract A series of three 4,4'-disubstituted-2,2'-bipyridines and the corresponding mononuclear cis-dichloro palladium(II) complexes have been synthesized. None of the ligands show mesomorphism. Upon their complexation to Pd(II) the peculiar structural arrangement characterized by intermolecular associations of the new derivatives induces mesogenic properties, confirming the new and exciting role of the coordination chemistry in metal-mediated formation of liquid crystals. Keywords: MetallomesogensPalladiumDialkyl 2,2′-bipyridine-4,4′-dicarboxylatesCoordination Compounds
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