纳米片
激进的
双酚A
电子顺磁共振
光催化
铋
催化作用
降级(电信)
面(心理学)
光化学
微球
化学
吸附
材料科学
化学工程
纳米技术
有机化学
五大性格特征
电信
核磁共振
计算机科学
人格
环氧树脂
心理学
工程类
物理
社会心理学
作者
Meilan Pan,Haijun Zhang,Guandao Gao,Lu Liu,Wei Chen
标识
DOI:10.1021/acs.est.5b00626
摘要
Photocatalysts with different exposed facets often exhibit different photochemical performances, but the underlying mechanisms are not fully understood. In this study, we synthesized two nanosheet-assembled bismuth oxyiodide (BiOI) microspheres with exposed (110) and (001) facets, respectively, to further investigate facet-dependent photocatalytic activity. Our experimental results showed that the BiOI microspheres with exposed (110) facets exhibited much greater catalytic activity than the BiOI microspheres with exposed (001) facets in the degradation of bisphenol A under visible light irradiation. Density functional theory calculation revealed that the (110) facets can adsorb a greater amount of O2 and, thus, form more O2(•-) and (•)OH radicals than the (001) facets. The electron spin resonance spectroscopy and radical scavenging experiments verified that the BiOI microspheres with exposed (110) facets could produce a greater amount of O2(•-) radicals than the BiOI microspheres with exposed (001) facets, and more importantly, between the two BiOI products, only the BiOI microspheres with exposed (110) facets could generate (•)OH radicals directly. The facet-dependent radical formation mechanisms were previously unidentified. The findings of this study may have important implications for the understanding of the facet-dependent photochemical performance of photocatalysts and the design of novel catalytic materials with inorganic nanostructures.
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