材料科学
分离器(采油)
阳极
复合数
锂(药物)
纳米片
氮化硼
离子
原子层沉积
图层(电子)
电流密度
热解炭
纳米技术
光电子学
化学工程
电极
复合材料
医学
化学
物理
工程类
物理化学
量子力学
内分泌学
热解
热力学
作者
Tao Ma,Rui Wang,Song Jin,Shibing Zheng,Lin Li,Jinqiang Shi,Yanfei Cai,Jing Liang,Zhanliang Tao
标识
DOI:10.1021/acsami.0c16354
摘要
It is difficult to achieve higher energy density with the existing system of lithium (Li)-ion batteries. As a powerful candidate, Li metal batteries are in the renaissance. Unfortunately, the uncontrolled growth process of Li dendrites has limited their actual application. Hence, inhibiting the formation and spread of Li dendrites has become an enormous challenge. Herein, a novel composite separator is developed with functionalized boron nitride nanosheet modification layer as a Li-ion regulator to regulate Li-ion fluxes. The composite separator contains abundant polar groups and nanoscale channels and could achieve uniform electrochemical deposition via the lithiophilic effect and shunting action. Under the synergy influence of the lithiophilic effect and shunting action, Li dendrites are effectively suppressed. As proof, the Li||Li symmetrical cells with composite separators can circulate steadily for a long time under high current densities (10 mA cm–2, 800 h). Moreover, the LiFePO4||Li full cells display excellent long cycling performance (82% retention after 800 cycles).
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