光催化
罗丹明B
石墨氮化碳
材料科学
介孔材料
氧化剂
降级(电信)
化学工程
兴奋剂
可见光谱
比表面积
多孔性
光化学
催化作用
化学
有机化学
复合材料
光电子学
工程类
电信
计算机科学
作者
Zesheng Li,Qianying Chen,Qiachun Lin,Ying Chen,Xichun Liao,Huiqing Yu,Changlin Yu
标识
DOI:10.1016/j.jtice.2020.09.019
摘要
As a typical metal-free photocatalyst, graphitic carbon nitride (g-C3N4) has attracted great attention for photocatalytic degradation of various organic pollutants. In this study, three-dimensional (3-D) phosphorus (P)-doped porous g-C3N4 nanosheets were prepared successfully via the thermal oxidation and element doping associated method. Abundant in-plane mesopores (from 2 nm to 50 nm), high specific surface area (202.9 cm2 g−1) and desirable P content (0.87%) were obtained for this 3-D P-doped porous g-C3N4 nanosheets. Taking Rhodamine B as a model pollutant, the photocatalytic properties of this 3-D P-doped porous g-C3N4 nanosheets photocatalyst were investigated, and the mechanism of photocatalytic degradation was also proposed. The 3-D P-doped porous g-C3N4 nanosheets showed the much enhanced visible-light photocatalytic activity, with Rhodamine B degradation ratio of 99.5% and a kinetic reaction rate constant of 0.120 min−1, compared to porous g-C3N4 nanosheets (58.2% and 0.031 min−1). The catalytic mechanism analysis shows that the active radicals of •OH and •O2− have strong oxidizing property, which can quickly decompose target organic dyes. The mesoporous structure and high P content of doping endowed photocatalyst with abundant active sites, high conductivity, and efficient separation of photoproduced electron-hole pairs.
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