化学
富勒烯
离子
电泳剂
氰化物
离子键合
四硫富瓦烯
盐(化学)
无机化学
茂金属
巴克敏斯特富勒烯
化学稳定性
有机化学
分子
聚合
催化作用
聚合物
作者
Pavel A. Troshin,Ekaterina A. Khakina,Аlexander S. Peregudov,Dmitri V. Konarev,Ilya V. Soulimenkov,Svetlana M. Peregudova,Rimma N. Lyubovskaya
标识
DOI:10.1002/ejoc.201000016
摘要
Abstract Reaction of C 60 Cl 6 with organic cyanide yielded an ionic salt comprising the fullerene anion [C 60 (CN) 5 ] – . This anion showed unprecedented stability in air and in solutions in the presence of water, organic and inorganic acids, and various electrophiles. The remarkable stability of the [C 60 (CN) 5 ] – anion opens wide opportunities for the design of various air‐stable salts incorporating different cations (metallocene, tetrathiafulvalene, and etc.) that might reveal valuable magnetic or electronic properties and find wide application in the field of material science.
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