High Yield of CO and Synchronous S Recovery from the Conversion of CO2 and H2S in Natural Gas Based on a Novel Electrochemical Reactor

H₂S and CO₂ are the main impurities in raw natural gas, which needs to be purified before use. However, the comprehensive utilization of H₂S and CO₂ has been ignored. Herein, we proposed a fully resource-based method to convert toxic gas H₂S and greenhouse gas CO₂ synchronously into CO and elemental S by using a novel electrochemical reactor. The special designs include that, in the anodic chamber, H₂S was oxidized rapidly to S based on the I^-/I₃^- cyclic redox system to avoid anode passivation. On the other hand, in the cathodic chamber, CO₂ was rapidly and selectively reduced to CO based on a porous carbon gas diffusion electrode (GDE) modified with polytetrafluoroethylene and cobalt phthalocyanine (CoPc). A high Faraday efficiency (>95%) toward CO was achieved due to the enhanced mass transfer of CO₂ on the GDE and the presence of the selective CoPc catalyst. The maximum energy efficiency of the system was more than 72.41% with a current density of over 50 mA/cm², which was 12.5 times higher than what was previously reported on the H₂S treatment system. The yields of S and CO were 24.94 mg·cm^-2·h^-1 and 19.93 mL·cm^-2·h^-1, respectively. A model analysis determined that the operation cost of the synchronous utilization of H₂S and CO₂ method was slightly lower than that of the single utilization of H₂S in the existing natural gas purification technology. Overall, this paper provides efficient and simultaneous conversion of H₂S and CO₂ into S and CO.