有机太阳能电池
材料科学
串联
光伏系统
光伏
有机半导体
光电子学
吸收(声学)
纳米技术
聚合物
电气工程
工程类
复合材料
作者
Dong Meng,Zhi Hua Ran,Yepin Zhao,Elizabeth Zhang,Letian Dou,Yang Yang
标识
DOI:10.1002/adma.202107330
摘要
Near-infrared (NIR)-absorbing organic semiconductors have opened up many exciting opportunities for organic photovoltaic (OPV) research. For example, new chemistries and synthetical methodologies have been developed; especially, the breakthrough Y-series acceptors, originally invented by our group, specifically Y1, Y3, and Y6, have contributed immensely to boosting single-junction solar cell efficiency to around 19%; novel device architectures such as tandem and transparent organic photovoltaics have been realized. The concept of NIR donors/acceptors thus becomes a turning point in the OPV field. Here, the development of NIR-absorbing materials for OPVs is reviewed. According to the low-energy absorption window, here, NIR photovoltaic materials (p-type (polymers) and n-type (fullerene and nonfullerene)) are classified into four categories: 700-800 nm, 800-900 nm, 900-1000 nm, and greater than 1000 nm. Each subsection covers the design, synthesis, and utilization of various types of donor (D) and acceptor (A) units. The structure-property relationship between various kinds of D, A units and absorption window are constructed to satisfy requirements for different applications. Subsequently, a variety of applications realized by NIR materials, including transparent OPVs, tandem OPVs, photodetectors, are presented. Finally, challenges and future development of novel NIR materials for the next-generation organic photovoltaics and beyond are discussed.
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