吸附
水溶液
朗缪尔吸附模型
水溶液中的金属离子
傅里叶变换红外光谱
吸热过程
纳米复合材料
材料科学
解吸
X射线光电子能谱
化学工程
无机化学
核化学
化学
金属
有机化学
纳米技术
工程类
作者
Norah Alhokbany,Tansir Ahamad,Mu. Naushad,Saad M. Alshehri
标识
DOI:10.1016/j.molliq.2019.111598
摘要
Fabrication of novel adsorbent with high surface area and high adsorption capacity is in urgent demand for water treatment, Therefore, in this study, a nanocomposite include Schiff base polymer and magnetic Fe3O4 nanoparticles was synthesized and characterized using analytical techniques including FTIR, TGA, XRD, Raman, SEM, TEM, XPS and N2 adsorption-desorption studies. The fabricated magnetic porous organic polymer (MPOP) was used as an efficient adsorbent for the removal of Cd(II) and Hg(II) from aqueous solution. The adsorption kinetic results revealed that both metal ions; Cd(II) and Hg(II) supported the pseudo-second-order adsorption kinetic model. The Langmuir isotherm model supported the adsorption over MPOP with a maximum adsorption capacity of 308.9 mg g−1 and 284.6 mg g−1 for Cd(II) and Hg(II), respectively. The thermodynamic results indicated that the adsorption of both metal ions was spontaneous and endothermic. The regeneration results suggested that the novel MPOP was a promising reusable adsorbent for the adsorption of heavy metal ions from aqueous solution.
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