Experimental Study on the Micromorphology and Strength Formation Mechanism of Epoxy Asphalt During the Curing Reaction

环氧树脂 材料科学 复合材料 固化(化学) 沥青 极限抗拉强度 傅里叶变换红外光谱 扫描电子显微镜 化学工程 工程类
作者
Wei Xu,Guoyi Zhuang,Zhengxiong Chen,Jintao Wei
出处
期刊:Applied sciences [Multidisciplinary Digital Publishing Institute]
卷期号:10 (7): 2610-2610 被引量:37
标识
DOI:10.3390/app10072610
摘要

The micromorphological changes and the strength formation mechanism of the curing of epoxy asphalt, which is mostly used for steel bridge deck pavements, were investigated. A tensile test was used to analyze the mechanical properties of epoxy asphalt, and Fourier transform infrared spectroscopy (FTIR) was used to determine the change in the epoxy peak area. Laser scanning confocal microscopy (LSCM) and scanning electron microscopy (SEM) were used to observe two-dimensional and three-dimensional micromorphological changes, respectively, during the curing reaction of epoxy asphalt. The results of the tensile and FTIR tests on epoxy asphalt showed that the tensile strength and epoxy conversion rate both increased with the curing time and exhibited similar trends, indicating that the network formed by the crosslinking and polymerization of epoxy groups causes the increased strength of epoxy asphalt. The curing degree of epoxy asphalt during the curing reaction can be indirectly evaluated from the conversion rate of epoxy groups. The asphalt tended to evenly be dispersed in the continuous phase of the epoxy resin during the formation of the epoxy resin network, and the network structure increased the deformation of the epoxy resin. The epoxy asphalt curing reaction process was classified into three stages based on the degree of curing.
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