Palladium‐Catalyzed N‐Arylation of N,N‐Dialkylhydrazines with Aryl Chlorides

Abstract N,N‐Dialkyl‐N′‐arylhydrazines have been prepared usually in high to excellent yields via the reaction of N,N‐dialkylhydrazines with aryl chlorides in the presence of Pd2(dba)3, Xphos and NaO‐t‐Bu in dioxane at 120 °C. With ortho‐substituted aryl chlorides best results have been obtained by using 2‐(2′,6′‐dimethoxybiphenyl)dicyclohexylphosphine (ligand d) as the ligand.