Nickel‐Catalyzed Cross‐Coupling of Non‐activated and Functionalized Alkyl Halides with Alkyl Grignard Reagents

Reacting in the 'Ni'ck of time: The title reaction is realized by using an isolated Ni(II) complex (1). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross-coupling reactions.