相间
聚合物
曲面(拓扑)
化学物理
放松(心理学)
材料科学
相(物质)
凝聚态物理
链条(单位)
纳米技术
物理
复合材料
生物
天文
社会心理学
量子力学
遗传学
数学
心理学
几何学
作者
Margarita Krutyeva,A. Wischnewski,M. Monkenbusch,Lutz Willner,Jon Maiz,Carmen Mijangos,Arantxa Arbe,Juan Colmenero,Aurel Rădulescu,Olaf Holderer,Michael Ohl,D. Richter
标识
DOI:10.1103/physrevlett.110.108303
摘要
We present neutron spin echo experiments that address the much debated topic of dynamic phenomena in polymer melts that are induced by interacting with a confining surface. We find an anchored surface layer that internally is highly mobile and not glassy as heavily promoted in the literature. The polymer dynamics in confinement is, rather, determined by two phases, one fully equal to the bulk polymer and another that is partly anchored at the surface. By strong topological interaction, this phase confines further chains with no direct contact to the surface. These form the often invoked interphase, where the full chain relaxation is impeded through the interaction with the anchored chains.
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