Low‐Overpotential Li–O2 Batteries Based on TFSI Intercalated Co–Ti Layered Double Oxides

Lithium–oxygen batteries with an exceptionally high theoretical energy density have triggered worldwide interest in energy storage system. The research focus of lithium–oxygen batteries lies in the development of catalytic materials with excellent cycling stability and high bifunctional catalytic activity in oxygen reduction and oxygen evolution reactions. Here, a hierarchically porous flower‐like cobalt–titanium layered double oxide on nickel foam with intercalated anions of bistrifluoromethane sulfonamide (TFSI) is designed and prepared. When used as a binder‐free cathode for lithium–oxygen batteries, this material exhibits low polarization (initial polarization of 0.45 V) and superior cycling stability (80 cycles at a current density of 100 mA g −1 at full discharge/charge). The high electrochemical performance of the cathode material is attributed to the good dispersion of binary elements in its host layer and good compatibility with lithium bistrifluoromethane sulfonamide electrolyte induced by intercalated guest anions of TFSI within its interlayer. This work provides a novel strategy for the fabrication of binder‐free cathodes based on layered double oxides for high‐performance lithium–oxygen batteries.