双金属片
选择性
铜
吸附
电化学
化学
金属
氧化还原
无机化学
材料科学
纳米技术
冶金
组合化学
催化作用
电极
有机化学
物理化学
作者
Anthony Vasileff,Chaochen Xu,Yan Jiao,Yao Zheng,Shi‐Zhang Qiao
出处
期刊:Chem
[Elsevier]
日期:2018-08-01
卷期号:4 (8): 1809-1831
被引量:592
标识
DOI:10.1016/j.chempr.2018.05.001
摘要
The electrochemical CO2 reduction reaction (CO2RR) can couple carbon-capture storage with renewable energy to convert CO2 into chemical feedstocks. For this process, copper is the only metal known to catalyze the CO2RR to hydrocarbons with adequate efficiency, but it suffers from poor selectivity. Copper bimetallic materials have recently shown an improvement in CO2RR selectivity compared with that of copper, such that the secondary metal is likely to play an important role in altering inherent adsorption energetics. This review explores the fundamental role of the secondary metal with a focus on how oxygen (O) and hydrogen (H) affinity affect selectivity in bimetallic electrocatalysts. Here, we identify four metal groups categorized by O and H affinities to determine their CO2RR selectivity trends. By considering experimental and computational studies, we link the effects of extrinsic chemical composition and physical structure to intrinsic intermediate adsorption and reaction pathway selection. After this, we summarize some general trends and propose design strategies for future electrocatalysts.
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