聚苯胺
石墨烯
材料科学
超级电容器
电极
化学工程
氧化物
阳极
法拉第效率
电容
阴极
纳米技术
复合材料
聚合物
化学
聚合
工程类
物理化学
冶金
作者
Hanping Xu,Zijie Lei,Mincai Xu,Jingqiao Zhu,Xinshan Song,Xiaojuan Jin
标识
DOI:10.1016/j.ijbiomac.2023.123934
摘要
This work demonstrates a facile and effective strategy for the preparation of a reduced graphene oxide/carboxymethylcellulose-polyaniline (RGO/CMC-PANI) hybrid film electrode. Specifically, through the hydrogen bonding interaction between -OH of CMC molecules and -NH2 of aniline monomer, PANI grows in an ordered manner on the surface of CMC, which effectively alleviates the structural collapse of PANI during the continuous charge/discharge process. After compounding with RGO, CMC-PANI bridges adjacent RGO sheets to form a complete conductive path, and opens the gap between RGO sheet layers to obtain fast ion channels. As a result, the RGO/CMC-PANI electrode exhibits excellent electrochemical performance. Moreover, an asymmetric supercapacitor was fabricated using RGO/CMC-PANI as the anode and Ti3C2Tx as the cathode. The results show that the device has a large specific capacitance of 450 mF cm-2 (81.8 F g-1) at 1 mA cm-2 and a high energy density of 140.6 μWh cm-2 at a power density of 749.9 μW cm-2. Besides, 87.3 % initial capacitance and 100 % good coulombic efficiency can be maintained even after 20,000 GCD cycles. Therefore, the device has a broad application prospect in the field of new-generation microelectronic energy storage.
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