Poly(arylene ether)s via Cu(II)-Catalysis

Poly(arylene ether)s (PAEs) are a versatile class of thermoplastic materials with commercial importance. Currently their synthesis relies predominantly on either nucleophilic or electrophilic aromatic substitution reactions, severely limiting the scope of available PAEs. Herein, we report the copper(II)-catalyzed polycondensation of electronically unactivated aryl bromides with bisphenols to afford a wide range of new PAEs. These PAEs are characterized by their thermal and mechanical properties. Functional PAEs were produced that have reversible acid- and redox-triggered chromophores incorporated into the backbone, which illustrates the utility of these methods.