Photo‐Stimulated Zn‐based Batteries: Progress, Challenges, and Perspectives

Abstract Solar energy, as a renewable energy source, dominates the vast majority of human energy, which can be harvested and converted by photovoltaic solar cells. However, the intermittent availability of solar energy restricts the actual utilization circumstances of solar cells. Integrating photo‐responsive electrodes into an energy storage device emerges as a dependable and executable strategy, fostering the creation of photo‐stimulated batteries that seamlessly amalgamate the process of solar energy collection, conversion, and storage in one system. Endowed by virtues such as cost‐effectiveness, facile manufacturing, safety, and environmental friendliness, photo‐stimulated Zn‐based batteries have attracted considerable attention. The progress report furnishes a brief overview, summarizing various photo‐stimulated Zn‐based batteries. Their configurations, operational principles, advancements, and the intricate engineering of photoelectrode designs are introduced, respectively. Through rigorous architectural design, photo‐stimulated Zn‐based batteries exhibit the ability to initiate charging by saving electricity usage, and in certain instances, even without the need for external electrical grids under illumination. Furthermore, the compensation of solar energy can be explored to improve the output electric energy. At last, opportunities and challenges toward photo‐stimulated Zn‐based batteries in the process of development are proposed and discussed in the hope of expanding their application scenarios and accelerating the commercialization progress.