Waste self-heating bag derived iron-based composite with abundant oxygen vacancies for highly efficient Fenton-like degradation of micropollutants

In this study, iron-rich waste self-heating bag was reutilized as the raw material to prepare oxygen vacancies (OV) functionalized iron-based composite (iron oxide (Fe3O4)-carbon-vermiculite, viz. OV-ICV), which exhibited excellent performance in the Fenton-like degradation of micropollutants via peroxydisulfate (PDS) activation. Above 95% of 1.0 mg/L carbaryl (CB) was efficiently eliminated in the presence of 0.1 g/L of OV-ICV and 0.5 mmol/L of PDS over a wide pH range of 3-10 within 30 min. Besides, OV-ICV also showed acceptable adaptability, stability, and renewability. Imbedding OV into Fe3O4 structure significantly generated more active iron sites and localized electrons, promoted the charge transfer ability, and assisted the redox cycle of ≡Fe(III)/≡Fe(II) for PDS activation. Mechanism investigation demonstrated that superoxide radicals (O2•-) derived from the activation of molecular oxygen mediated the generation of H2O2, and both of them further enhanced the formation of more sulfate radicals (SO4•-) and hydroxyl radicals (•OH), which led to the efficient degradation and mineralization of CB. Furthermore, the degradation pathways of CB were proposed based on the intermediates identification. This work lays a foundation for the rational reutilization of iron-containing wastes modified with defect engineering in heterogeneous Fenton-like catalysis for the remediation of micropollutants wastewater.