Smart and programmed thermo-wetting yarns for scalable and customizable moisture/heat conditioning textiles

Programmable smart textiles with adaptive moisture/heat conditioning (MHC) capabilities are globally being sought to meet the requirements of comfort, energy efficiency, and health protection. However, a universal strategy for fabricating truly scalable and customizable MHC textiles is lacking. In this study, we introduce a scalable in situ grafting approach for the continuous fabrication of two series of smart textile yarns with opposite thermoresponsive wetting behaviors. In particular, the wetting transition temperature can be precisely programmed by adjusting the grafting formula, making the yarns highly customizable. The smart yarns demonstrated excellent mechanical strength, whiteness, weavability, biocompatibility, and washability (with more than 60 home washes), comparable to those of regular textile yarns. They can serve as building blocks independently or in combination to create smart textiles with adaptive sweat wicking and intelligent moisture/heat regulation capabilities. A proposed hybrid textile integrating both the two series of smart yarns can offer dry-contact and cooling/keep-warming effects of approximately 1.6/2.8 °C, respectively, in response to changes in ambient temperature. Our method provides a rich array of design options for nonpowered MHC textiles while maintaining a balance between traditional wearing conventions and large-scale production.