膜
质子交换膜燃料电池
侧链
材料科学
质子
三氟甲磺酸
化学工程
电导率
相对湿度
聚合物
相(物质)
高分子化学
化学
催化作用
有机化学
复合材料
物理化学
工程类
物理
热力学
量子力学
生物化学
作者
Hongyun Tan,Shengqiu Zhao,S. Eltahir Ali,Shuhong Zheng,Abdullah K. Alanazi,Rui Wang,Haining Zhang,Hala M. Abo‐Dief,Ben Bin Xu,Hassan Algadi,Handong Li,Priyanka Wasnik,Zhanhu Guo,Haolin Tang
标识
DOI:10.1016/j.jmst.2023.03.049
摘要
Structural optimization of ionomers is an effective strategy for achieving high-performance proton exchange membranes (PEMs) under low relative humidity (RH) conditions. In this study, sulfonimide group and trifluoromethanesulfonate acid (TFSA) ionic liquids were introduced to the perfluorosulfonic acid (PFSA) side chain, resulting in polymer membranes with varying chain lengths (i.e., PFC2-TF-SI, PFC4-TF-SI, and PFC5-TF-SI). This dual proton-conducting structure extended the length of the hydrophilic side chain and enhanced the hydrophobic-hydrophilic phase separation, aiding in the formation of proton transport channels. Notably, the proton conductivity of PFC5-TF-SI and PFC2-TF-SI membranes reached 7.1 and 10.6 mS/cm at 30% RH and 80 °C, respectively, which were approximately 29.1% and 92.7% higher than that of the pristine PFC5-SA membrane (5.5 mS/cm). Furthermore, the maximum power density of the PFC5-TF-SI and PFC2-TF-SI membranes from the built single fuel cell achieved 649 and 763 mW/cm2 at 30% RH and 80 °C, respectively, which were higher than that of the pristine PFC5-SA membrane (567 mW/cm2) by about 14.5% and 34.6%, respectively. Thus, this study provides a strategy for PEM design under low RH conditions.
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