电解质
膜
水溶液
化学
扩散
焊剂(冶金)
离子交换
离子交换树脂
离子
强电解质
化学工程
色谱法
热力学
无机化学
有机化学
物理化学
电极
生物化学
物理
工程类
作者
Joanna Mackie,P. Meares
出处
期刊:Proceedings of the Royal Society of London
[The Royal Society]
日期:1955-11-22
卷期号:232 (1191): 498-509
被引量:447
标识
DOI:10.1098/rspa.1955.0234
摘要
An equation for the flux of electrolyte through a water-swollen cation-exchange resin membrane separating two solutions of the same electrolyte at different concentrations is derived on the basis of several assumptions regarding the physical nature of a swollen resinous exchanger. The complete flux equation contains three terms, one determined by the concentration difference across the membrane, another determined by the variation of the activity coefficient of the electrolyte with concentration in the membrane and a third concerned with the rate of osmotic or hydrostatic flow through the membrane. If ions in the resin are transported entirely in an internal aqueous phase, the mobilities required for the flux equation can be related to mobilities in aqueous solution and to the volume fraction of resin in the swollen membrane. The treatment is readily extended to anion exchangers.
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