Oriented Gradient Doping of Zirconium in Ni-Rich Cathode to Achieve Ultrahigh Stability and Rate Capability

after 300 cycles. Furthermore, the Zr-doped cathode delivered significant stability at a high potential of 4.5 V with a capacity retention of 72.1% after 300 cycles, while that of the bare sample was only 37.4%. The concept of gradient doping strategies during coprecipitation offers new insight into the design of advanced cathodes with excellent cycling stability and rate capability.