Combined with the performance of rutile titanium dioxide,the inorganic surface treatment mechanism and process of titanium dioxide were introduced. The influences of dispersion of TiO 2 particles-suspension,pH,addition and adding sequence of coating agent,reaction time and temperature were investigated,and the technique of inorganic coating with Si-Al was obtained. Results showed that prepared TiO 2 powder with the technique of Si-Al,its whiteness was greater than 93. 7%,lightening power was between 110 ~ 113,with excellent weather-ability.