沸石咪唑盐骨架
放射性核素
咪唑酯
环境科学
生化工程
化学
金属有机骨架
纳米技术
材料科学
工程类
吸附
物理
有机化学
量子力学
作者
Elvis Djam Miensah,Musaa Muhammad Khan,Jiu Yu Chen,Xiao Mei Zhang,Peng Wang,Zong Xiang Zhang,Jiao Yan,Ying Liu,Yi Yang
标识
DOI:10.1080/10643389.2019.1686946
摘要
High-energy demands due to globalization have led to the proliferation of nuclear technology as an alternative greener energy source to meet these demands. With this proliferation comes the release of large amounts of radionuclides into the environment. Zeolitic imidazolate frameworks (ZIFs) with tunable porous structures and numerous active sites have proved to be excellent at removing these radionuclides from various environmental media. These active sites due to the presence of functional groups allow for favorable sorptive interactions between ZIF-based materials and radionuclides. With their excellent chemical stability in refluxing organic and aqueous media, ZIFs hold a special place among metal-organic framework materials with respect to capturing various types of radionuclides. Moreover, other favorable characteristics such as high thermal stability, high framework porosities (ZIF-8 surface area as high as 1970 m2 g−1) and abundant functional groups, make them suitable for capturing radionuclides. In this review, recent advances in the sequestration of radionuclides with ZIFs and their derived materials (composites, derivatives) are highlighted. The challenges and prospects in this fast-growing branch of coordination chemistry are briefly discussed. This work, being the first of its kind to the best of our knowledge will serve as grounding for the future development of ZIF-based materials for radionuclide removal from the environment.
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