Electrocatalytic Reduction of Nitrate via Co3O4/Ti Cathode Prepared by Electrodeposition Paired With IrO2-RuO2 Anode

Nitrate pollution is already a global problem, and the electrocatalytic reduction of nitrate is a promising technology for the remediation of wastewater and polluted water bodies. In this work, Co 3 O 4 /Ti electrodes were prepared by electrodeposition for the electrocatalytic reduction of nitrate. The morphology, chemical, and crystal structures of Co 3 O 4 /Ti and its catalytic activity were investigated. Then, the electrocatalytic nitrate reduction performance of Co 3 O 4 /Ti as the cathode was evaluated by monitoring the removal efficiencies of nitrate (NO 3 − -N) and total nitrogen (TN), generation of reduction products, current efficiency (CE), and energy consumption (EC) at different operating conditions. Under the catalysis of Co 3 O 4 /Ti, NO 3 − was reduced to N 2 and NH 4 + , while no NO 2 − was produced. After the introduction of chloride ions and IrO 2 -RuO 2 /Ti as the anode, NH 4 + was selectively oxidized to N 2 . The removal efficiencies of NO 3 − -N (at 100 mg/L) and TN after 2 h were 91.12% and 60.25%, respectively (pH 7.0; Cl − concentration, 2000 mg/L; current density, 15 mA/cm 2 ). After 4 h of operation, NO 3 − -N and TN were completely removed. However, considering the EC and CE, a 2-h reaction was the most appropriate. The EC and CE were 0.10 kWh/g NO 3 − N and 40.3%, respectively, and electrocatalytic performance was maintained after 10 consecutive reduction cycles (2 h each). The cathode Co 3 O 4 /Ti, which is prepared by electrodeposition, can effectively remove NO 3 − -N, with low EC and high CE.