钙钛矿(结构)
化学物理
重组
离子键合
离子
磁滞
电子
扩散
存水弯(水管)
材料科学
化学
分子物理学
凝聚态物理
物理
结晶学
热力学
气象学
基因
量子力学
有机化学
生物化学
作者
Daniel Walter,Andreas Fell,Yiliang Wu,Chog Barugkin,Nandi Wu,Thomas P. White,Klaus Weber
标识
DOI:10.1021/acs.jpcc.8b02529
摘要
It is highly probable that perovskite solar cells (PSCs) are mixed electronic-ionic conductors, with ion migration being the driving force for PSC hysteresis. However, there is much that is not understood about the interaction of ion migration with other processes in the cell. The key question is: what factors of a PSC are influenced when ions are free to move? In this contribution, we employ a numerical drift-diffusion model of PSCs to show that the migration of both anions and cations in interaction with trap-mediated recombination in the bulk and/or at the surfaces of the perovskite absorber can manifest both current–voltage hysteresis and unusual nonmonotonic PSC photovoltage transients. We identify that a key mechanism of this interaction is the influence of the net ionic charge throughout the perovskite bulk—which varies as the ions approach new steady-state conditions—on the distribution of electrons and holes and subsequently the spatial distribution of trap-mediated recombination modeled after Shockley Read Hall (SRH) statistics. Relative to intrinsic recombination mechanisms, SRH recombination can be highly sensitive to local asymmetries of the electron–hole population. We show that this sensitivity is key to replicating nonmonotonic transients with multiple time constants, the forms of which may have suggested multiple processes. This work therefore supports the conceptualization of the hysteretic behavior of PSCs as dominated by the interplay between ion migration and trap-mediated recombination throughout the perovskite absorber.
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