尼亚尔
制氢
光催化
材料科学
氢氧化物
氢
催化作用
化学工程
过电位
异质结
光化学
无机化学
化学
复合材料
电化学
金属间化合物
光电子学
物理化学
有机化学
工程类
电极
合金
作者
Dujuan Li,Xiuli Ma,Peng Su,Shengjiang Yang,Zhibo Jiang,Youji Li,Zhiliang Jin
标识
DOI:10.1016/j.mcat.2021.111990
摘要
NiAl-LDH was completely phosphate to obtain Ni2P with strong adsorption characteristics, and a simple physical stirring method was used to fix Ni2P in the 3D layered double hydroxide NiAl-LDH layer to obtain a new type of Ni2P@NiAl-LDH (NNP) S-scheme heterojunction catalyst. The Ni2P obtained by phosphating process can provide 3D reaction sites for photoelectrons and absord photogenerated carriers to participate in the photocatalytic reaction. Moreover, the S-scheme interface heterojunction can directionally change the transfer path of electric charges and improve the effective utilization of electrons. The hydrogen evolution test results show that the hydrogen production of the composite material NNP-3 (Ni2P-15%@NiAl-LDH) within 5 h can reach 107.62 μmol (2152.4 μmolg−1 h−1), 17.27 times and 2.59 times of NiAl-LDH and Ni2P, respectively. And after 25 h hydrogen production cycle, the composite catalyst still has a high hydrogen production rate and showed strong stability. Optical tests show that the composite material Ni2P@NiAl-LDH (NNP) has a strong visible light capturing ability and can increase the absorption range of visible light. Photochemical tests show that the use of Ni2P to modify NiAl-LDH can reduce the overpotential of hydrogen evolution, accelerate the transfer of photoelectrons and improve the utilization of electrons. This research provides a new idea for improving the performance of NiAl-LDH using the phosphating process, and provides an effective method for NiAl-LDH to participate in the photocatalytic hydrogen evolution technology with high efficiency.
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