聚合
聚合物
单体
香兰素
材料科学
共聚物
高分子化学
乳液聚合
亚胺
甲基丙烯酸酯
丙烯酸酯
有机化学
化学工程
化学
催化作用
工程类
作者
Jules Stouten,Maria K.N. de Roy,Katrien V. Bernaerts
标识
DOI:10.1016/j.mtsust.2023.100396
摘要
In the effort toward the production of circular plastics, the use of lignin-derived aromatic building blocks such as vanillin is interesting due to their functionality. Nonetheless, the water-borne emulsion polymerization of acrylic monomers derived from vanillin is still lacking. Vanillin can be readily functionalized with a methacrylate group for the radical polymerization to yield polymers containing functional aldehyde side groups. The functionality can be exploited via imine formation to produce vitrimers, a class of cross-linked recyclable polymers. Besides recycling, synthesis via a water-borne emulsion polymerization is desired to reduce the negative contribution of solvents on the environment and health. In the present work, polymethacrylates based on 2-(methacryloyloxy)ethyl vanillin and 2-octyl acrylate were synthesized via a emulsion polymerization approach to produce a water-borne latex. A latex with a small particle size (49 nm) and solid content of 31 wt% was obtained. For comparative purposes, a similar polymer was synthesized via solution polymerization. Both polymers were cross-linked using a multifunctional amine to produce recyclable imine vitrimers. This research investigates the unique combination of water-borne synthesis and vitrimer polymers, and therefore contributes to future development of vitrimer latex products such as coatings and films.
科研通智能强力驱动
Strongly Powered by AbleSci AI