色素敏化染料
材料科学
煅烧
静电纺丝
微晶
化学工程
扫描电子显微镜
傅里叶变换红外光谱
纳米材料
四方晶系
纳米线
太阳能电池
纳米技术
比表面积
电解质
电极
复合材料
光电子学
化学
晶体结构
催化作用
结晶学
工程类
物理化学
生物化学
冶金
聚合物
作者
Weronika Smok,Tomasz Tański,A. Drygała,Jacek Podwórny
标识
DOI:10.1016/j.apsusc.2022.154850
摘要
Using a hybrid sol–gel and electrospinning method, one-dimensional SnO2 nanostructures were fabricated with average diameters of 86 and 53 nm after calcination at 500 and 600 °C, respectively. The morphology and structure of the obtained materials were analyzed using transmission and scanning electron microscopy (TEM, SEM) and X-ray diffraction (XRD). Additionally, the chemical composition was confirmed using Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Based on BET and BJH analysis, the specific surface area and porosity of SnO2 nanowires were evaluated. The optical properties of the prepared materials were investigated by UV–Vis spectrophotometer. The analyses confirmed that polycrystalline SnO2 nanostructures composed of two polymorphic varieties tetragonal and rhombohedral were derived, whose calcination temperature had a significant effect on the diameter, specific surface area and energy gap width. The fabricated nanowires were added at 5 and 10 mg to P25 TiO2 paste and screen-printed onto FTO substrate. After drying and calcination, the TiO2 NPs-SnO2 NWs hybrid photoanode was charged with dye, electrolyte and platinum electrode were applied and its performance was investigated in a dye-sensitized solar cell (DSSC). The study showed that the addition of 5 mg SnO2 increased the cell efficiency by 12% compared to the standard P25. The results presented in this study are a good base for further research and shows how important it is to work on the application of nanomaterials produced by the electrospinning technique, which will help to develop and increase the efficiency and competitiveness of DSSC.
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