Layered MXene Films via Self‐Assembly

Abstract MXene has attracted significant attention as a 2D material family due to its metallic conductivity and abundant surface functional groups and has been extensively studied and applied as bulk materials and microscale thin films. MXene possesses ionizable surfaces and edges, as well as high surface area. Its customizable dispersibility demonstrates unique advantages in self‐assembly solution processing. Recent studies have demonstrated the application value of layered MXene films at the nanoscale thickness and the reliance of processing on self‐assembly techniques. However, this field currently lacks sufficient attention. Here, the regulatory mechanisms are summarized for the preparation of layered MXene films through self‐assembly techniques, as well as introduce their applications. Moreover, the future challenges of large‐scale applications of MXene self‐assembly techniques are proposed. It is believed that this review would provide a dynamic and promising path for the development of layered MXene self‐assembly techniques.