Three in One: Three Different Molybdates Trapped in a Thiacalix[4]arene Protected Ag72 Nanocluster for Structural Transformation and Photothermal Conversion

nanocluster based 1D chain structure (Ag28a), respectively. Moreover, the post-synthesized Ag28a can be utilized as potential ignition material for further application. This work not only provides an important model for unlocking dynamic features of POMs at atom-precise level but also pioneers a promising approach to synthesize silver nanoclusters from known to unknown.