层状结构
电化学
化学
电极
硫黄
化学工程
金属有机骨架
纳米技术
结晶学
材料科学
物理化学
有机化学
工程类
吸附
作者
Teng Ma,Xiao Liu,Xiaowen Wang,Jian‐Gong Ma,Peng Cheng
标识
DOI:10.1021/acs.inorgchem.4c00862
摘要
Lamellar metal–organic frameworks (MOFs) have attracted significant attention in the field of electrochemical sensing due to their abundant open active sites and specific electron conductivity. Herein, by employing a bottom-up synthesis strategy, rhombic lamellar heterometallic CoNi-MOFs with varying thicknesses are constructed. This is achieved by using 4-methylpyridine as a capping agent based on the (4,6)-linked Co2(azpy)2(bptc) (azpy = 4,4′-azopyridine, bptc = 3,3′,5,5′-biphenyltetracarboxylic acid) structure with a fsc topology and by introducing Ni species simultaneously. To mitigate sulfur deposition on electrodes, the triple pulse amperometry (TPA) method is employed. Among the synthesized lamellar CoNi-MOFs, lamellar CoNi-MOF-3 with the minimum thickness exhibits an optimal electrochemical sensing performance toward hydrogen sulfide, with a sensitivity of 119.3 μA·mM–1·cm–2 in the linear range of 2–2000 μM. This study pioneers a new approach to the controlled construction and electrochemical activity modification of lamellar MOF materials.
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