金属化
钯
配体(生物化学)
共价键
催化作用
胺气处理
化学
铃木反应
组合化学
高分子化学
有机化学
受体
生物化学
作者
Jaewoong Lim,Seonghwan Lee,Hyeonbin Ha,Junmo Seong,Seok Jeong,Min Kim,Seung Bin Baek,Myoung Soo Lah
标识
DOI:10.1002/anie.202102898
摘要
Amine-tagged defective Ni-MOF-74 was prepared by solvothermal synthesis using aminosalicylic acid as a functionalized fragmented ligand, as described by Seung Bin Baek, Myoung Soo Lah et al. in their Communication on page 9296. The covalent post-synthetic modification and subsequent post-synthetic metalation with palladium(II) ions affords a palladium(II)-incorporated Ni-MOF-74 catalyst, which exhibits highly efficient, size-selective, and recyclable catalytic activity for the Suzuki–Miyaura coupling reaction.
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