介电谱
材料科学
扫描电子显微镜
腐蚀
接触角
电化学
极化(电化学)
电极
开路电压
涂层
冶金
复合材料
化学工程
分析化学(期刊)
核化学
色谱法
电压
化学
物理
物理化学
量子力学
工程类
作者
Sevgi Ateş,Evrim Baran Aydın,Birgül Yazıcı
标识
DOI:10.1080/01694243.2020.1807240
摘要
In the present work, SnO2 was successfully coated on mild steel (MS) by the sol–gel method at different times (15,30,45 min). These coatings were developed to improve the performance of corrosion protection of MS in a 0.5 M HCl solution. The morphological and structural characterization of obtained electrodes was investigated with the help of characterized by Field-emission scanning electron microscopy (FE-SEM) and the contact angle. The corrosion behavior of uncoated and at 15,30,45 min SnO2-coated MS electrodes were investigated by open circuit potential (OCP)–time, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques in 0.5 M HCl solution at 20–50 °C. Moreover, the potential of zero charges (pzc) of MS was determined using the EIS technique. EIS results indicated that the maximum inhibition efficiency (85%) during the coating time of 30 min at 30 °C. As a result, the SnO2 film effectively protected on the MS against corrosion and reduced its corrosion rate in the HCl solution.HighlightsThe SnO2 was coated on MS electrode at 15, 30, 45 minutes by a simple sol-gel method.The surface morphologies were characterized by FE-SEM and the contact angle.The corrosion behaviors of samples were investigated by electrochemical techniques.The SnO2 provides good corrosion protection against the attack of corrosive media.
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