多面体
丝带
化学
扩展(谓词逻辑)
棒
结晶学
对称(几何)
金属有机骨架
网(多面体)
联动装置(软件)
金属
螺旋(腹足类)
几何学
纳米技术
材料科学
计算机科学
数学
有机化学
吸附
生态学
病理
程序设计语言
替代医学
基因
生物
医学
生物化学
蜗牛
作者
Alexander Schoedel,Mian Li,Dan Li,Michael O′Keeffe,Omar M. Yaghi
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2016-09-14
卷期号:116 (19): 12466-12535
被引量:726
标识
DOI:10.1021/acs.chemrev.6b00346
摘要
Rod MOFs are metal-organic frameworks in which the metal-containing secondary building units consist of infinite rods of linked metal-centered polyhedra. For such materials, we identify the points of extension, often atoms, which define the interface between the organic and inorganic components of the structure. The pattern of points of extension defines a shape such as a helix, ladder, helical ribbon, or cylinder tiling. The linkage of these shapes into a three-dimensional framework in turn defines a net characteristic of the original structure. Some scores of rod MOF structures are illustrated and deconstructed into their underlying nets in this way. Crystallographic data for all nets in their maximum symmetry embeddings are provided.
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