材料科学
聚合物
执行机构
乙二醇
纳米线
红外线的
光热治疗
聚乙二醇
化学工程
纳米复合材料
纳米技术
光电子学
复合材料
光学
物理
工程类
电气工程
作者
Yue Zhou,Junyan Tan,Dandan Chong,Xinhua Wan,Jie Zhang
标识
DOI:10.1002/adfm.201901202
摘要
Abstract Photoresponsive actuators are built by introducing oligo(ethylene glycol) (OEG)‐modified W 18 O 49 nanowires into cross‐linked polyethylene glycol diacrylate (cPEGDA) polymer matrices. Due to the good compatibility, OEG‐W 18 O 49 NWs disperse well and increase the crystallinity of cPEGDA matrices even in high loading concentrations (4.0 wt%). The cPEGDA/W 18 O 49 nanocomposites show efficient photothermal transition and rapid shape memory behaviors. They can raise the local temperature to 160 °C in only 8.5 s and recover the initial shape within 10 s. Making use of the broad and strong absorption property of W 18 O 49 , the cPEGDA/W 18 O 49 NW actuators respond to both ultraviolet and near‐infrared light and make contraction and bending motions. Furthermore, by utilizing oriented chain segments of the crystalline polymer and vector sum of shape recovery forces, the cPEGDA/W 18 O 49 NW hybrid actuators exhibit stable helical deformation (right‐handed and left‐handed).
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