聚吡咯
材料科学
超级电容器
导电体
导电聚合物
电化学
金属有机骨架
聚合
纳米技术
电导率
结晶
化学工程
电极
聚合物
复合材料
有机化学
化学
吸附
物理化学
工程类
作者
Yu Han,Chuanyao Liu,Wenzhe Yue,Aisheng Huang
标识
DOI:10.1016/j.matlet.2022.132158
摘要
The poor electrical conductivity of the metal organic frameworks (MOFs) limits their application in the supercapacitors. Here we developed a versatile strategy to effectively incorporate the conductive polymer polypyrrole (PPy) into ZIF-67 by in-situ polymerization and crystallization. Attributed to the stereoscopic surrounding of ZIF-67 with the conductive PPy, which is helpful for fast transfer of the electron/ion, the ZIF-67/PPy heteroaerogel exhibits a high specific capacity (1241F g−1 at 1A g−1) and high stability with 91% retention rate after 10,000 cycles measurement at 10 A g−1. The appealing electrochemical performance of the ZIF-67/PPy heteroaerogel recommends its promising application in supercapacitors.
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